Exactly. Responsive is the key element. If she's only responsive once a week it's not responsive desire.
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She's responsive when she feels she can
be responsive, given her life/work/schedule/responsibilities. That's my interpretation of it anyway and I could be wrong.
Out of curiosity: what would happen if you asked
her explicitly whether you could have sex with her on a Wednesday once (if she has the time) and if she would explicitly disallow it?
My perception is (and I could be wrong) that she is not that type of 'controlling' personality.
My understanding is that he also does not like the fact that she is 'responsive' in the first place (as in, he would prefer it if she found ways to show him, that sex to her
is at least as important as it is to him. What does this mean in practice: it seems the only way for him to feel this, would be if she initiated sex at more frequent intervals than him, otherwise she will forever remain responsive
in his eyes which he is not that keen on. It is not a small thing to ask/expect to change in her personality, and IMV debatable whether it is reasonable too, given risks of breaking something that sort of works for both already, because it requires some expectation of rewiring of her personality from her part).